Formulation for the Performance Analysis of a Lithium-Carbon Monofluoride Cell
Downloads
The formulation presented in this paper is for the performance analysis of a primary lithium-carbon monofluoride cell. The formulation can also be used to compute the theoretical cell open-circuit voltage; the fractional conversion of the limiting reactant, carbon monofluoride and hence, the cell fractional state-of-charge; total amount of charge required to be involved for the complete utilization of the cell cathode active material, carbon monofluoride as well as the transient specific amount of charge involved; the ratio of the thermal energy production to the electric energy production; and the rate of heat exchange between the cell exterior surface and its surroundings required for the determination of the cell average temperature.
Sandhu, S. S.; Kosir, S. T.; Fellner, J. P. Thermal energy production and heat exchange between an electrochemical cell and its surroundings. RA J Appl Res. 2021: 07(09): 2497-2502. DOI: 10.47191/rajar/v7i9.03.
Sandhu, S. S.; Chen, P.; Fellner, J. P. On the diffusion-controlled transport and accumulation of lithium in an electrode of a lithium-based galvanic cell. RA J Appl Res. 2022: 08(01): 41-46. DOI: 10.47191/rajar/v8i1.08.
McCabe W.L.; Smith J.C.; Harriott P. Unit Operations of Chemical Engineering. pp. 376-379, 434, 435 (7th ed.), McGraw-Hill: 2005.
McAdams, W. H. Heat transmission. McGraw-Hill: 1954.
Ding, Z.; Yang, C.; et al. Reaction mechanism and structural evolution of fluorographite cathodes in Li/Na/K batteries. Research Square, DOI: 10.21203/rs.3.rs-39097/v1.
Wood, J. L.; et al. Thermodynamic, Electrochemical and Synthetic Studies of the Graphite-Fluorine Compounds CF and C4F. National Technical Information Service 1972, 755, 934.
Leung, Kevin, et al. Edge-propagation discharge mechanism in CF_x batteries -- a first-principles and experimental study. CM (chemistry of materials). 2021. DOI: 10.1021/acs.chemmater.0c04676.
J. Valerga, et al. Thermodynamic and Kinetic Data of Carbon-Fluorine Compounds. Final Report, March 1974, Report number: 410041; U.S. Army Electronics Command; Fort, Monmouth, New Jersey 07703.
All Content should be original and unpublished.